Synthesis, crystal structure and photophysical properties of a series of new neutral iridium(III) complexes with 2-phenylpyridine

Abstract: A series of new neutral iridium(III) complexes containing strong-field ancillary ligands, [Ir(ppy)2(PPh3)L] (ppy=2-phenylpyridine, PPh3 =triphenylphosphine, L=NCS−, 1; , 2; NCO−, 3), have been synthesized and fully characterized by 1H NMR, IR, ESI mass spectral and elemental analysis. The crystal structure of 1 has been determined by X-ray analysis. The photoluminescence (PL) spectra of 1–3 show emission maxima at 477, 489 and 485nm, respectively, corresponding to blue light-emitting of 1 and blue-green light-emitting of 2 and 3. PL quantum yields (PLQYs) of 1–3 are 0.39, 0.13 and 0.43, respectively. [Copyright &y& Elsevier]