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A convenient titanium-mediated intermolecular alkyne–carbonate coupling reaction

Authors :
Wolan, Andrzej
Cadoret, Frédéric
Six, Yvan
Source :
Tetrahedron. Sep2009, Vol. 65 Issue 36, p7429-7439. 11p.
Publication Year :
2009

Abstract

Abstract: A direct diastereoselective titanium-mediated intermolecular coupling of internal alkynes with dialkyl carbonates under Kulinkovich-type reaction conditions is presented. The influence of the structures of the coupling partners on the yields and regioselectivities of this transformation is described. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00404020
Volume :
65
Issue :
36
Database :
Academic Search Index
Journal :
Tetrahedron
Publication Type :
Academic Journal
Accession number :
43611515
Full Text :
https://doi.org/10.1016/j.tet.2009.07.015