Strong Hydrogen Binding within a 3D Microporous Metal—Organic Framework.

A 3D microporous cadmium(ll) metal-organic framework based on 1 H-tetrazole exhibits strong hydrogen binding with an initial enthalpy of adsorption of 13.3 kJ/mol, due to the smaller pore sizes and the high hydrogen binding affinity of the tetrazolyl-ringdecorated inner surface of the pores. [ABSTRACT FROM AUTHOR]