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Azoimidazolium iodocuprate(I) and iodoargentate(I)
- Source :
-
Polyhedron . Nov2009, Vol. 28 Issue 16, p3586-3592. 7p. - Publication Year :
- 2009
-
Abstract
- Abstract: 1,3-Di-alkyl-2-(arylazo)imidazolium iodide () has been used to prepare iodocuprate(I) and iodoargentate(I) complexes. The structural confirmation has been carried out by single crystal X-ray diffraction study in representative cases. Iodo bridged anion, [Cu2(μ-I)2I2]2−, serves as charge support to dialkylazoimidazolium ion (). Silver(I) compound is a trimeric iodo-bridged [Ag3I5]2− that forms 1D chain while imidazolium ion, , is penetrating into the network. Electrostatic interaction between organic cation and inorganic anion and supramolecular interactions viz. hydrogen bonding, D–H–π, π–π interactions contribute to the crystal packing. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 02775387
- Volume :
- 28
- Issue :
- 16
- Database :
- Academic Search Index
- Journal :
- Polyhedron
- Publication Type :
- Academic Journal
- Accession number :
- 44699147
- Full Text :
- https://doi.org/10.1016/j.poly.2009.07.034