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An Olefination via Ruthenium-Catalyzed Decarbonylative Addition of Aldehydes to Terminal Alkynes.
- Source :
-
Journal of the American Chemical Society . 10/28/2009, Vol. 131 Issue 42, p15092-15093. 2p. 2 Charts. - Publication Year :
- 2009
-
Abstract
- The article focuses on the development of a novel olefination method using decarbonylative addition of alkynes and aldehydes. It states that an alkene is generated when an alkyne is added during carbon—hydrogen (C—H) activation of aldehydes. It also notes that a high chemoselectivity was observed during the aromatic and aliphatic aldehydes chemical reaction.
- Subjects :
- *CHEMICAL reactions
*ALKYNES
*ALDEHYDES
*CHEMICAL bonds
*CHEMICAL processes
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 131
- Issue :
- 42
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 45241479
- Full Text :
- https://doi.org/10.1021/ja906265a