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Synthesis and characterization of mercury(II)–sugar thioureas complexes

Authors :
Maza, Susana
López, Óscar
Maya, Inés
Fernández-Bolaños, José G.
Source :
Polyhedron. Dec2009, Vol. 28 Issue 18, p4039-4043. 5p.
Publication Year :
2009

Abstract

Abstract: The synthesis of a novel class of mercury(II) complexes with sugar-derived bidentade isothioureido ligands, by treatment of N-acylated thioureas with an excess of yellow mercury(II) oxide in aqueous acetonitrile is reported. The 1:2 coordination stoichiometry of the complexes were confirmed by elemental analysis, mass spectrometry and NMR spectroscopy, and they were found to be consistent with a four-coordinate geometry. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
02775387
Volume :
28
Issue :
18
Database :
Academic Search Index
Journal :
Polyhedron
Publication Type :
Academic Journal
Accession number :
45420733
Full Text :
https://doi.org/10.1016/j.poly.2009.09.006