Back to Search
Start Over
Molecular self-organization of metal aminothiazoleacetate complexes into H-bonded metallo-supramolecular network based on and synthons
- Source :
-
Polyhedron . Dec2009, Vol. 28 Issue 18, p4077-4083. 7p. - Publication Year :
- 2009
-
Abstract
- Abstract: Two new isostructural d10 metal complexes, M(AmThAA)2 (M=Zn(II), Cd(II); AmThAA=2-amino, 3-thiazoleacetate), with square pyramidal geometries have been synthesized and characterized by elemental analysis, single-crystal X-ray diffraction and TG analysis. Both complexes crystallize in a monoclinic crystal system, having the C 2/c space group, which by utilizing built-in hydrogen-bonding groups (−NH2 and −COO−) extends the molecular complexes into hydrogen-bonded metallo-supramolecular networks. It has been shown that heteromeric N−HO and O−HO hydrogen bonds based on and supramolecular synthons can be relied upon as effective tools for the assembly and organization of penta-coordinated complexes. Furthermore, both compounds show strong photoluminescence properties at room temperature. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 02775387
- Volume :
- 28
- Issue :
- 18
- Database :
- Academic Search Index
- Journal :
- Polyhedron
- Publication Type :
- Academic Journal
- Accession number :
- 45420739
- Full Text :
- https://doi.org/10.1016/j.poly.2009.09.025