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Complex Hydrides with (BH4)- and (NH2)- Anions as New Lithium Fast-Ion Conductors.

Authors :
Motoaki Matsuo
Remhof, Arndt
Martelli, Pascal
Caputo, Riccarda
Ernst, Matthias
Yohei Miura
Toyoto Sato
Hiroyuki Oguchi
Hideki Maekawa
Hitoshi Takamura
Borgschulte, Andreas
Züttel, Andreas
Shin-ichi Orimo
Source :
Journal of the American Chemical Society. 11/18/2009, Vol. 131 Issue 45, p16389-16391. 3p. 3 Graphs.
Publication Year :
2009

Abstract

The article features the research on the significance of complex hydrides with (BH4)- and (NH2)- as new lithium fast-ion conductors. When researchers heated these hydrides, these metals exhibited lithium fast-ion conductivity of 2 x 10-4 Siemen per centimeter (S/cm) at ~370 Kelvin (K). Moreover, they concluded that the combination of complex hydrogen anions provide new occupation site for Li+ ions.

Details

Language :
English
ISSN :
00027863
Volume :
131
Issue :
45
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
45686751
Full Text :
https://doi.org/10.1021/ja907249p