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Luminescent boracite-like metal–organic frameworks constructed by Cu-centered CuCu4tetrahedra and CuCu3triangles with an acentric cubic superlarge cellElectronic supplementary information (ESI) available: Experimental details, XPRD patterns for 1–3and additional figures. CCDC reference numbers 731918–731920. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b918159h

Authors :
Zheng-Ming Hao
Cai-Hong Guo
Hai-Shun Wu
Xian-Ming Zhang
Source :
CrystEngComm. Jan2010, Vol. 12 Issue 1, p55-58. 4p.
Publication Year :
2010

Abstract

Solvothermal treatment of copper halides and 3-amino-5-mercapto-1,2,4-triazole (H2amtz) produced three isostructural complexes [Cu31X4(H1.55amtz)24](SO4)8·xDMF [X = Cl, Br and I, x∼ 32], which show 3-D networks with bortopology constructed by Cu-centered CuCu4tetrahedra and CuCu3triangles with an acentric cubic superlarge cell. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14668033
Volume :
12
Issue :
1
Database :
Academic Search Index
Journal :
CrystEngComm
Publication Type :
Academic Journal
Accession number :
46835489
Full Text :
https://doi.org/10.1039/b918159h