Back to Search
Start Over
Evidence To Support the Hypothesis That Promoting Vibrations Enhance the Rate of an Enzyme Catalyzed H-Tunneling Reaction.
- Source :
-
Journal of the American Chemical Society . 12/2/2009, Vol. 131 Issue 47, p17072-17073. 2p. - Publication Year :
- 2009
-
Abstract
- The article examines the origin of rate enhancement of flavin mono-nucleotide (FMN). It states that FMN reduction can be monitored as a pseudo-first-order reaction using single-turnover approaches. It suggests that the difference in observed rate between two near identical coenzymes is related to a vibrational mode present in the pentaerythritol tetranitrate reductase (PETNR) NADPH complex.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 131
- Issue :
- 47
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 46974665
- Full Text :
- https://doi.org/10.1021/ja908469m