New Mode of Coordination for the Dinitrogen Ligand: Formation, Bonding, and Reactivity of a....

Authors :: Fryzuk, Michael D.
Johnson, Samuel A.
Patrick, Brian O.
Albinati, Alberto
Mason, Sax A.
Koetzle, Thomas F.
Source :: Journal of the American Chemical Society. 05/02/2001, Vol. 123 Issue 17, p3960. 14p. 14 Diagrams, 4 Charts.
Publication Year :: 2001
Abstract: Examines the reactivity a tantalum complex with a bridging nitrogen unit. Synthesis of dinitrogen complexes; Reduction of dinitrogen moiety via reductive hydrogen elimination; Application of density functional theory calculations; Interactions involved in the side-on end-on bonding dinitrogen complex.

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