Hydrogen production with a solar steam–methanol reformer and colloid nanocatalyst

Abstract: In the present study a small steam–methanol reformer with a colloid nanocatalyst is utilized to produce hydrogen. Radiation from a focused continuous green light laser (514nm wavelength) is used to provide the energy for steam–methanol reforming. Nanocatalyst particles, fabricated by using pulsed laser ablation technology, result in a highly active catalyst with high surface to volume ratio. A small novel reformer fabricated with a borosilicate capillary is employed to increase the local temperature of the reformer and thereby increase hydrogen production. The hydrogen production output efficiency is determined and a value of 5% is achieved. Experiments using concentrated solar simulator light as the radiation source are also carried out. The results show that hydrogen production by solar steam–methanol colloid nanocatalyst reforming is both feasible and promising. [Copyright &y& Elsevier]