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Asymmetric ?-Aminoxylations of Stoichiometric Ketones Using 2-Nitrosotoluene.

Authors :
Jiao, Peng
Source :
Synlett. Sep2009, Vol. 2009 Issue 16, p2685-2687. 3p.
Publication Year :
2009

Abstract

Asymmetric aminoxylations of a stoichiometric amount of ketones were accomplished through O-nitrosoaldol reactions of 2-nitrosotoluene catalyzed by a proline-based tetrazole. The advantages of 2-nitrosotoluene and the tetrazole over nitrosobenzene and proline, respectively, were demonstrated. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09365214
Volume :
2009
Issue :
16
Database :
Academic Search Index
Journal :
Synlett
Publication Type :
Academic Journal
Accession number :
47729795
Full Text :
https://doi.org/10.1055/s-0029-1217750