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Enantioselective Synthesis of (+)-Cephalostatin 1.
- Source :
-
Journal of the American Chemical Society . 1/13/2010, Vol. 132 Issue 1, p275-280. 6p. - Publication Year :
- 2010
-
Abstract
- This Article describes an enantioselective synthesis of cephalostatin 1. Key steps of this synthesis are a unique methyl group selective allylic oxidation, directed C-H hydroxylation of a sterol at C12, Au(I)- catalyzed 5-endo-dig cyclization, and a kinetic spiroketalization. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 132
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 48230220
- Full Text :
- https://doi.org/10.1021/ja906996c