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Synthesis and characterization of organophosphine/phosphite stabilized silver(I) complexes bearing 2-acetyl-1,3-indandione ligand, crystal structure of [Ph3P·AgC11H7O3]
- Source :
-
Polyhedron . Apr2010, Vol. 29 Issue 6, p1687-1691. 5p. - Publication Year :
- 2010
-
Abstract
- Abstract: Six organophosphine/phosphite stabilized silver(I) complexes of 2-acetyl-1,3-indandione (2-AID) of type L n ·AgC11H7O3 (L=PPh3; n =1, 2a; n =2, 2b; L=P(OMe)3; n =1, 2c; n =2, 2d; L=P(OEt)3; n =1, 2e; n =2, 2f) have been prepared by reacting of [AgC11H7O3], which could be obtained by reacting of 2-AID with AgNO3, with triphenylphosphine, trimethylphosphite, or triethylphosphite in 1:1–2M ratio. These complexes were obtained in high yields and characterized by elemental analysis, 1H, 13C{H} NMR, IR spectroscopy, and thermal analysis (TG and DSC), respectively. The molecular structure of 2a has been determined by X-ray single crystal analysis in which the silver atom is in a distorted trigonal geometry. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 02775387
- Volume :
- 29
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Polyhedron
- Publication Type :
- Academic Journal
- Accession number :
- 48893819
- Full Text :
- https://doi.org/10.1016/j.poly.2010.02.017