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New reaction of β-diketiminatoeuropium complex: sterically induced oxidation–coupling of β-diketiminato ligandsCCDC 761013–761015. For crystallographic data in CIF or other electronic format see DOI: 10.1039/b927582g.
- Source :
-
Chemical Communications . 6/21/2010, Vol. 46 Issue 23, p4118-4120. 3p. - Publication Year :
- 2010
-
Abstract
- Attempted synthesis of sterically demanding tris-β-diketiminate complexes of europium led to oxidation–coupling of β-diketiminates and the formation of the THF-solvated divalent europium complex Eu(L2,6-Me2)2(THF) (L2,6-Me2= [{N(2,6-Me2C6H3)C(Me)}2CH]−), while the normal tris-β-diketiminate complex Eu(L2-Me)3for the less bulky ligand L2-Me([{N(2-MeC6H4)C(Me)}2CH]−) was isolated by the same procedure. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 46
- Issue :
- 23
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 51166520
- Full Text :
- https://doi.org/10.1039/b927582g