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Binuclear, 2D grid and 3D interlocking coordination polymers based on 1,2,4,5-benzenetetracarboxylic acid and 4,4′-azobispyridine
- Source :
-
Inorganic Chemistry Communications . Sep2010, Vol. 13 Issue 9, p1014-1017. 4p. - Publication Year :
- 2010
-
Abstract
- Abstract: Three new nickel(II) complexes [Ni2(btec)(azopy)2(H2O)8]·2H2O (1), {[Ni(H2btec)(azopy)(H2O)2]·(azopy)} n (2) and {[Ni4(btec)2(azopy)3(H2O)10]·8H2O} n (3) (H4btec=1,2,4,5-benzenetetracarboxylic acid; azopy=4,4′-azobispyridine) have been synthesized by tuning the reaction temperature and the metal–ligand ratio. They were characterized by single-crystal X-ray diffraction and elemental analysis. 1 shows a binuclear structure, 2 exhibits a 2D grid, and 3 features an interesting 3D framework with (63)(4.62)(42.62.82) topology formed by two types of interlocked 2D layers. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 13
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 52581268
- Full Text :
- https://doi.org/10.1016/j.inoche.2010.05.018