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Synthesis and Crystal Structure of a Fe(III) Complex with an Isonicotinyl Hydrazone Ligand, [Fe(N-Isonicotinamidosalicylaldimine)Cl2].
- Source :
-
Journal of Chemical Crystallography . Sep2010, Vol. 40 Issue 9, p726-730. 5p. - Publication Year :
- 2010
-
Abstract
- A new complex [Fe(N-isonicotinamidosalicylaldimine)Cl2] has been synthesized by template reaction at room temperature and structurally characterized by X-ray single-crystal analysis. The complex crystallizes in triclinic crystal system, Pī space group, a = 7.273(6) Å, b = 10.015(8) Å, c = 10.479(8) Å, α = 71.067(10)°, β = 89.964(11)°, γ = 75.528(10)°, V = 696.4(9) Å3 and Z = 2. The coordination geometry around the Fe(III) ion is a distorted trigonal bipyramid with a O2N1Cl2 donor set. In the crystal structure, N–H···Cl, C–H···O and C–H···Cl hydrogen bonds and π···π stacking interactions involving aromatic and unclosed π-systems link the molecules to form supramolecular double layers. A new Fe(III) complex of N-isonicotinamidosalicylaldimine, an isonicotinyl hydrazone ligand, has been prepared and crystallographically characterized. [Figure not available: see fulltext.] [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10741542
- Volume :
- 40
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Journal of Chemical Crystallography
- Publication Type :
- Academic Journal
- Accession number :
- 52691982
- Full Text :
- https://doi.org/10.1007/s10870-010-9726-6