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Evidence of preferential π-stacking: a study of intermolecular and intramolecular charge transfer complexesElectronic supplementary information (ESI) available: Detailed description of synthesis, MS, IR 1H-NMR, 13C-NMR, optical spectra, and Rehm–Weller analysis. See DOI: 10.1039/c0cc00249f
- Source :
-
Chemical Communications . 8/14/2010, Vol. 46 Issue 30, p5464-5466. 3p. - Publication Year :
- 2010
-
Abstract
- Nine combinations of π-electron donors and acceptors were examined by UV-vis, fluorescence and 1H-NMR spectroscopy to identify π-stacked charge transfer complexes in macromolecular and supramolecular constructs. The high association constant of pyrene and naphthalene diimide suggests a preferentially π-stacking pair rationalized by frontier orbital congruence. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 46
- Issue :
- 30
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 52703759
- Full Text :
- https://doi.org/10.1039/c0cc00249f