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Vibrational Coupling and Hydrogen Bonding at the Air/Water Interface.
- Source :
-
AIP Conference Proceedings . 8/6/2010, Vol. 1267 Issue 1, p115-116. 2p. 1 Graph. - Publication Year :
- 2010
-
Abstract
- The ‘Free OH’ stretch mode observed by sum-frequency generation (SFG) vibrational spectroscopy presents a unique probe of the H-bonding at the air/water interface. This relatively narrow transition is well separated from the much broader and red-shifted part of the water OH-stretch band, thus permitting frequency-domain spectroscopic analysis. Furthermore, water molecules with the ‘free OH’ are only found in the top-most monolayer at the interface, which eliminates the ambiguity of the probe location (depth) in the interface. [ABSTRACT FROM AUTHOR]
- Subjects :
- *HYDROGEN bonding
Subjects
Details
- Language :
- English
- ISSN :
- 0094243X
- Volume :
- 1267
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- AIP Conference Proceedings
- Publication Type :
- Conference
- Accession number :
- 52721033
- Full Text :
- https://doi.org/10.1063/1.3482357