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Rhodium-catalyzed enantioselective alkynylative cyclization of allenyl aldehydes with terminal alkynes
- Source :
-
Tetrahedron: Asymmetry . Jul2010, Vol. 21 Issue 13/14, p1730-1736. 7p. - Publication Year :
- 2010
-
Abstract
- Abstract: Asymmetric addition of terminal alkynes to allenyl aldehydes took place in the presence of an acetylacetonate complex [Rh(acac)L∗] (L∗=binap or segphos) as a catalyst to give indanol derivatives in high yields with high regio- and enantioselectivity. The acetylacetonate (acac) ligand on the rhodium is important for the selective formation of the indanol derivatives. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09574166
- Volume :
- 21
- Issue :
- 13/14
- Database :
- Academic Search Index
- Journal :
- Tetrahedron: Asymmetry
- Publication Type :
- Academic Journal
- Accession number :
- 52820461
- Full Text :
- https://doi.org/10.1016/j.tetasy.2010.04.039