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Absorption of NO into NaClO3/NaOH solutions in a stirred tank reactor

Authors :
Guo, Rui-tang
Gao, Xiang
Pan, Wei-guo
Ren, Jian-xing
Wu, Jiang
Zhang, Xiao-bo
Source :
Fuel. Nov2010, Vol. 89 Issue 11, p3431-3435. 5p.
Publication Year :
2010

Abstract

Abstract: The absorption kinetics of NO into aqueous solutions of NaClO3/NaOH was investigated under different experimental conditions in a stirred tank reactor. It is proven that the absorption process is a fast pseudo-mth reaction. The reaction was found to be second-order with respect to NO and first-order with respect to NaClO3. The frequency factor and average activation energy of this reaction were 2.696×106 m3/(mols) and 13.88kJ/mol, respectively. The addition of NaOH to solutions of NaClO3 decreased the absorption rate of NO. And the absorption rate of NO increased with increasing reaction temperature. In this study, the flue gas flow rate almost had little effect on the absorption of NO. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00162361
Volume :
89
Issue :
11
Database :
Academic Search Index
Journal :
Fuel
Publication Type :
Academic Journal
Accession number :
52822101
Full Text :
https://doi.org/10.1016/j.fuel.2010.03.020