Use of Hesperaloe funifera for the production of paper and extraction of lignin for synthesis and fuel gases

Abstract: In this work, we characterized Hesperaloe funifera; pulp and paper obtained by subjecting the plant raw material to soda, soda–anthraquinone, ethanolamine, ethyleneglycol and diethyleneglycol cooking. In addition, the solid fractions extracted by acidifying the cooking liquors, rich in lignin, were used to obtain synthesis and fuel gases. The contents in lignin, α-cellulose, holocellulose, hemicellulose, ethanol–benzene extractives, hot water solubles, 1% NaOH solubles and ash of H. funifera were found to be 7.3%, 40.9%, 76.5%, 35.6%, 4.0%, 13.5%, 29.5% and 5.9%, respectively. The mean fibre length, 4.19 mm, exceeds those for some non-wood materials. Hesperaloe pulp obtained by cooking with 10% NaOH and 1% anthraquinone at 155 °C for 30 min exhibited good values of yield (48.3%), viscosity (737 mL g−1), Kappa number (15.2), tensile index (83.6 Nm g−1), stretch (3.8%), burst index (7.34 kN g−1) and tear index (3.20 mNm2 g−1). Acidification to pH 6 of the liquor resulting from the soda pulping of 500 g of plant raw material provided an amount of 13.90 g of lignin-rich solids pyrolysis of which gave a gas mixture containing 1.13% H2, 31.79% CO and 1.86% CH4 by weight. Gasification of the same sample provided a mixture containing 0.18% H2, 24.50% CO and 17.75% CH4, also by weight. [ABSTRACT FROM AUTHOR]