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Highly enantioselective hydroaminoalkylation of secondary amines catalyzed by group 5 metal amides with chiral biarylamidate ligands.

Authors :
Zi, Guofu
Zhang, Furen
Song, Haibin
Source :
Chemical Communications. 9/14/2010, Vol. 46 Issue 34, p6296-6298. 3p.
Publication Year :
2010

Abstract

A highly enantioselective group 5 metal amide catalyst system is reported for the hydroaminoalkylation of secondary amines to give chiral amines in good yields with excellent ee values (up to 93%) by loading of 5% precatalyst. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
46
Issue :
34
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
53377267
Full Text :
https://doi.org/10.1039/c0cc01265c