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C1-Symmetric Dicyclopentadienes as New Chiral Diene Ligands for Asymmetric Rhodium-Catalyzed Arylation of N-Tosylarylimines.
- Source :
-
Organic Letters . Sep2010, Vol. 12 Issue 17, p3820-3823. 4p. - Publication Year :
- 2010
-
Abstract
- Monosubstituted C1-symmetric dicyclopentadienes as a new class of diene ligands have been developed for asymmetric arylation of N-tosylarylimines in excellent yields (98â99%) with high enantioselectivities (90â96%). The preparation of these diene ligands relied on an efficient lipase-catalyzed resolution as the key step. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15237060
- Volume :
- 12
- Issue :
- 17
- Database :
- Academic Search Index
- Journal :
- Organic Letters
- Publication Type :
- Academic Journal
- Accession number :
- 53378794
- Full Text :
- https://doi.org/10.1021/ol101531r