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lonothermal Synthesis of Layered Zirconium Phosphates and Their Tribological Properties in Mineral Oil.

Authors :
Lei Liu
Zhao-Feng Chen
Hai-Bo Wei
Yang Li
Yu-Chuan Fu
Hong Xu
Jin-Ping Li
Slawin, Alexandra M. Z.
Jin-Xiang Dong
Source :
Inorganic Chemistry. 9/20/2010, Vol. 49 Issue 18, p8270-8075. 6p.
Publication Year :
2010

Abstract

In an attempt to synthesize novel zirconium phosphate materials, a series of syntheses have been performed in a deep eutectic solvent (DES), composed of tetrapropylammonium bromide (TPABr) and oxalic acid. As a result, this DES does not act as a template provider in reaction probably owing to the steric effects of the longer chains of the TPA cation, and only the α-Zr(HPO4)2∙H2O (α-ZrP) phase has been achieved. However, after organic amine was added to the initial reaction mixture in a normal way, the additives did act as a template to induce the zirconium phosphate framework. For example, with 1,4-dimethylpiperazine as an additive, a novel layered compound, [C6H16N2]0.5Zr- (H0.5PO4)2∙H2O (denoted as ZrPO4-DES8) was obtained. Its structure was determined from single-crystal X-ray diffraction (XRD) data and consists of zirconium phosphate layers with the protonated 1 ,4-dimethylpiperazine and water molecules in between. Interestingly, the two layered materials as additives in a liquid lubricant exhibit excellent friction behavior with higher load-carrying and antiwear capacities in comparison to typical lubricant additives such as MoS2 and graphite, increase the PB value of the base oil by 27.2% and 8.5%, and decrease the wear scar diameter of the base oil by 43% and 36%, respectively. Scanning electron microscopy, XRD, and energy-dispersive X-ray spectrometry are used to investigate the lubricant behavior of those materials. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00201669
Volume :
49
Issue :
18
Database :
Academic Search Index
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
54058534
Full Text :
https://doi.org/10.1021/ic100657a