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Broadband composite spin-state-selective rotations for NMR spectroscopy on partially aligned molecules.
- Source :
-
Journal of Chemical Physics . 11/8/2001, Vol. 115 Issue 18, p8506. 12p. 4 Diagrams, 1 Chart, 3 Graphs. - Publication Year :
- 2001
-
Abstract
- Composite spin-state-selective rotations are introduced. They are devised to remedy the following problem: When determining scalar plus residual dipolar couplings by conventional NMR experiments in partially aligned molecules, a considerable variation in the effective coupling constant often entails systematic errors compromising the accuracy of the measurements. The concept of composite pulses is extended in order to design spin-state-selective composite rotations (S[sup 3]CR) robust to variation in effective coupling constants. With the S[sup 3]CR approach the broadband performance of spin-state-selective excitation improves significantly as is demonstrated both numerically and experimentally. © 2001 American Institute of Physics. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00219606
- Volume :
- 115
- Issue :
- 18
- Database :
- Academic Search Index
- Journal :
- Journal of Chemical Physics
- Publication Type :
- Academic Journal
- Accession number :
- 5420586
- Full Text :
- https://doi.org/10.1063/1.1408621