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A new vanadium Schiff base complex as catalyst for oxidation of alcohols.
- Source :
-
Journal of Coordination Chemistry . Nov2010, Vol. 63 Issue 21, p3849-3858. 10p. 3 Diagrams, 3 Charts, 2 Graphs. - Publication Year :
- 2010
-
Abstract
- The monoanionic bidentate Schiff base, N-(phenolyl)-benzaldimine (HL), has been employed to synthesize a new vanadium(IV) complex of general composition [VO(L)2] (where L = O, N donor of Schiff base). The ligand and complex have been fully characterized by elemental analyses, molar conductance data, FT-IR, 1H- and 13C-NMR, and UV-Vis spectroscopies. Oxidation of alcohols to their corresponding aldehydes and ketones was conducted by this complex catalyst using Oxone as oxidant under biphasic reaction conditions (CH2Cl2/H2O) and tetra-n-butylammonium bromide as phase transfer agent under air at room temperature. [ABSTRACT FROM AUTHOR]
- Subjects :
- *SCHIFF bases
*VANADIUM
*LIGANDS (Chemistry)
*ALDEHYDES
*KETONES
Subjects
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 63
- Issue :
- 21
- Database :
- Academic Search Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 54419333
- Full Text :
- https://doi.org/10.1080/00958972.2010.520316