Improved interfacial properties of carbon fiber/epoxy composites through grafting polyhedral oligomeric silsesquioxane on carbon fiber surface

Abstract: Carbon fibers were grafted with a layer of uniform octaglycidyldimethylsilyl POSS in an attempt to improve the interfacial properties between carbon fibers and epoxy matrix. Atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and dynamic contact angle analysis were performed to characterize the carbon fibers. AFM results show that the grafting of POSS significantly increased the carbon fiber surface roughness. XPS indicates that oxygen-containing functional groups obviously increased after modification. Dynamic contact angle analysis shows that the surface energy of modified carbon fibers is much higher than that of the untreated ones. Results of the mechanical property tests show that interlaminar shear strength (ILSS) increased from 68.8 to 90.5MPa and impact toughness simultaneously increased from 2.62 to 3.59J. [ABSTRACT FROM AUTHOR]