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Rapid Biomimetic Total Synthesis of (±)-Rossinone B.
- Source :
-
Organic Letters . Dec2010, Vol. 12 Issue 23, p5554-5557. 4p. - Publication Year :
- 2010
-
Abstract
- A biomimetic total synthesis of (±)-rossinone B has been achieved through a highly efficient strategy featuring a series of rationally designed reactions, including a one-pot allylic rearrangement/oxidation reaction to generate the vinyl quinone 27, an intramolecular vinyl quinone Diels−Alder reaction to construct the linear 6−6−5 tricyclic core of 28, and a double conjugate addition/β-elimination cascade to complete the total synthesis of 1. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15237060
- Volume :
- 12
- Issue :
- 23
- Database :
- Academic Search Index
- Journal :
- Organic Letters
- Publication Type :
- Academic Journal
- Accession number :
- 55497078
- Full Text :
- https://doi.org/10.1021/ol102438r