Orientation Dependence of Electrical Properties of Bi3.15Pr0.85Ti3O12 Thin Films.

Randomly oriented and c-axis-oriented Bi3.15Pr0.85Ti3O12 (BPT) thin films were prepared by a chemical solution deposition method. Ferroelectric and leakage current properties were strongly related to the crystallographic orientation of BPT thin film. The values of remnant polarization (2Pr) and leakage current density were 74 μC/cm2 at 250 kV/cm and 3.4 × 10-8 A/cm2 at 125 kV/cm for the randomly oriented thin film, respectively, and 16 μC/cm2 and 6.9 × 10-6 A/cm2 for the c-axis-oriented thin film, respectively. The result indicates that the polarization vector of BPT thin films is not oriented along the c-axis. [ABSTRACT FROM AUTHOR]