Fabrication of microporous hollow silica spheres templated by NP-10 micelles without calcinations

Abstract: We reported a novel method to fabricate hollow silica microspheres using nonionic surfactant nonyl phenol ethoxylated decylether (NP-10) micelles as template, n-octadecane as core and sodium silicate as silica precursor. The core materials were removed by ethanol during the reaction. Hollow structure formed without calcinations or chemical etching. Hierarchical silica hollow microspheres were prepared by changing the concentration of the reactants and reaction time. Size of the core materials was obtained from the temperature-dependent dynamic light scattering (DLS) measurement. Scanning election microscopy (SEM) and transmission electron microscopy (TEM) results revealed that ordered microporous hollow silica microspheres with thickness of shell about 200nm and mean diameter 2.5μm were prepared. Porosity and pore size were analyzed by Brunauer–Emmett–Teller (BET). [ABSTRACT FROM AUTHOR]