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Cooperative catalysis in highly enantioselective Mannich-type three-component reaction of a diazoacetophenone with an alcohol and an imineElectronic supplementary information (ESI) available: Experimental details and characterisation of new compounds. See DOI: 10.1039/c0cc03024d
- Source :
-
Chemical Communications . Dec2010, Vol. 47 Issue 2, p797-799. 3p. - Publication Year :
- 2010
-
Abstract
- A highly enantioselective three-component reaction of a diazoacetophenone, an alcohol, and an imine catalyzed cooperatively by Rh2(OAc)4and BINOL-derived chiral phosphoric acid has been developed for the synthesis of chiral β-amino-α-hydroxyl ketones in good yield with excellent diastereo and enantio selectivity. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 47
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 57567101