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Two new hybrid compounds assembled from Keggin-type polyoxometalates and transition metal coordination complexes
- Source :
-
Journal of Solid State Chemistry . Mar2011, Vol. 184 Issue 3, p557-562. 6p. - Publication Year :
- 2011
-
Abstract
- Abstract: Two new hybrid compounds based on Keggin-type polyoxometalates: {[PMo12O40][Ni(Phen)2(H2O)]2}·K·2OH− (1) and [Cd2(Phen)4Cl2][HPW12O40]·H2O (2) (Phen=1,10-phenanthroline), have been prepared and characterized by IR, UV–vis, XPS, XRD and single crystal X-ray diffraction analyses. Compound 1 exhibits a 1-D chain structure constructed from Pseudo-Keggin polyoxometalate bi-supported transition metal coordination complexes linked by K+ ions. Compound 2 contains Pseudo-Keggin polyoxoanions [HPW12O40]2− and novel metal–chloride–ligand coordination complexes [Cd2(Phen)4Cl2]2+. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 00224596
- Volume :
- 184
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Journal of Solid State Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 59320550
- Full Text :
- https://doi.org/10.1016/j.jssc.2011.01.009