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Synthesis, Characterisation and Magnetic Properties of a One-Dimensional Iron(II) Coordination Polymer.
- Source :
-
Journal of Chemical Crystallography . May2011, Vol. 41 Issue 5, p601-605. 5p. 3 Diagrams, 2 Charts, 2 Graphs. - Publication Year :
- 2011
-
Abstract
- A new iron(II) coordination polymer, [FeCl(NCH)(NCH)], has been synthesized under solvothermal conditions and structurally characterized by single-crystal X-ray diffraction. This material crystallizes in the monoclinic space group C2/c, with a = 11.2850(6), b = 13.8925(7), c = 17.0988(9) Å and β = 94.300(3)º ( Z = 4). The crystal structure consists of neutral zig-zag chains, in which the iron(II) ions are octahedrally coordinated. The infinite polymer chains are packed into a three-dimensional structure through C-H···Cl interactions. Magnetic susceptibility measurements reveal the existence of weak antiferromagnetic interactions between the iron(II) ions. The effective magnetic moment, μ = 5.33 μ, is consistent with a high-spin iron(II) configuration. Graphical Abstract: The crystal structure of the coordination polymer [FeCl(NCH)(NCH)] consists of neutral zig-zag chains, in which the iron(II) ions are octahedrally coordinated.[Figure not available: see fulltext.] [ABSTRACT FROM AUTHOR]
- Subjects :
- *IRON
*COORDINATION polymers
*SPACE groups
*ANTIFERROMAGNETISM
*CRYSTALLOGRAPHY
Subjects
Details
- Language :
- English
- ISSN :
- 10741542
- Volume :
- 41
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Journal of Chemical Crystallography
- Publication Type :
- Academic Journal
- Accession number :
- 59671698
- Full Text :
- https://doi.org/10.1007/s10870-010-9930-4