Total syntheses of (+)-monomorine I and (−)-indolizidine 195B from sulfinimine-derived 3-oxo pyrrolidine 2-phosphonates

Authors :: Davis, Franklin A.
Zhang, Junyi
Wu, Yongzhong
Source :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Apr2011, Vol. 52 Issue 17, p2054-2057. 4p.
Publication Year :: 2011
Abstract: Abstract: Indolizidine alkaloids (+)-monomorine I (1) and (−)-indolizidine 195B (2), having cis and trans relationships of the C-3 and C-9 substituents, respectively, were prepared from the sulfinimine-derived chiral building blocks N-sulfinyl δ-amino β-ketophosphonate and 3-oxo pyrrolidine 2-phosphonate. [Copyright &y& Elsevier]

Subjects :: *ORGANIC synthesis
*IMINES
*PYRROLIDINE
*PHOSPHONATES
*ALKALOIDS
*CHIRALITY
*CHEMICAL reactions

Language :: English
ISSN :: 00404039
Volume :: 52
Issue :: 17
Database :: Academic Search Index
Journal :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :: Academic Journal
Accession number :: 59814939
Full Text :: https://doi.org/10.1016/j.tetlet.2010.10.076

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