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Self-Assembly Syntheses and Crystal Structure of a New Organotin(IV) Schiff Base Complex Containing a Novel SnO Hydrolysis Ladder.
- Source :
-
Journal of Inorganic & Organometallic Polymers & Materials . Sep2007, Vol. 17 Issue 3, p541-546. 6p. - Publication Year :
- 2007
-
Abstract
- new organotin(IV) Schiff base complex 4 containing a novel SnO hydrolysis ladder and a disulfide group has been synthesized through a self-assembly reaction. The complex 4 has been characterized by elemental analysis, IR, H-, C-, and Sn-NMR spectra and X-ray crystallography diffraction analyses. The study of the supramolecular structure of complex 4 found that there exist two kinds of C-H···S and C-H···O intermolecular hydrogen bonds. The two kinds of intermolecular hydrogen bonds force the complex 4 into a 2-dimensional 'wave' network. The geometry about each tin atom involved is distorted trigonal bipyramid. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15741443
- Volume :
- 17
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Journal of Inorganic & Organometallic Polymers & Materials
- Publication Type :
- Academic Journal
- Accession number :
- 59996107
- Full Text :
- https://doi.org/10.1007/s10904-007-9146-z