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A novel 2D coordination polymer based on triangular-shaped [Mn3O] units bridged by sodium ions and benzene-1,2,4,5-tetracarboxylate
- Source :
-
Inorganic Chemistry Communications . Jun2011, Vol. 14 Issue 6, p997-1000. 4p. - Publication Year :
- 2011
-
Abstract
- Abstract: On the basis of triangular-shaped [Mn3O] secondary building units, a novel two-dimensional (2D) manganese(III) complex, [NaMnIII 3O(sao)3(btec)0.5(H2O)3]·1.25H2O (1) (H2sao=salicylaldoxime, H4btec=benzene-1,2,4,5-tetracarboxylate acid), was synthesized and structurally characterized. The structure of 1 consists of 2D coordination polymer based on [Mn3O] units bridged by sodium ions and benzene-1,2,4,5-tetracarboxylate groups. Magnetic data analysis shows that antiferromagnetic couplings exist between the manganese(III) ions in [Mn3O] subunit of complex 1. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 14
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 60522619
- Full Text :
- https://doi.org/10.1016/j.inoche.2011.03.054