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Two new self-penetrating metal-organic frameworks based on a flexible cyclohexanetetracarboxylate ligand
- Source :
-
Inorganic Chemistry Communications . Jun2011, Vol. 14 Issue 6, p822-825. 4p. - Publication Year :
- 2011
-
Abstract
- Abstract: Two new metal-organic frameworks, [M2(CTA)(bipy)1.5(H2O)2] n ·3n(H2O) (M=Cd for 1 and Mn for 2, H4CTA=cyclohexane-1,2,4,5-tetracarboxylic acid, bipy=4,4′-bipyridine) have been successfully synthesized and characterized. Complexes 1 and 2 are isostructural, which display unusual three-dimensional (3D) self-penetrating coordination frameworks with 3-nodal (3,5,5)-connectivity and the Schläfli symbol of (4,6,8)(42,67,8)(43,63,83,9). Moreover, in solid state, complex 1 exhibits blue emission at ambient temperature. Magnetic measurement shows that there exist weak antiferromagnetic interactions in 2. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 14
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 60522628
- Full Text :
- https://doi.org/10.1016/j.inoche.2011.02.018