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Enantioselective αAmination of Branched Aldehydes Promoted by Simple Chiral Primary Amino Acids.
- Source :
-
Journal of Organic Chemistry . 6/3/2011, Vol. 76 Issue 11, p4661-4664. 3p. - Publication Year :
- 2011
-
Abstract
- A series of simple chiral primary amino acids were first successfully applied to promote the enantioselective α-amination of branched aldehydes with azadicarboxylates and the desired adducts bearing quaternary stereogenic centers were obtained in excellent yields (up to 99%) and enantioselectivities (up to 97% ee). [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALDEHYDES
*AMINO acids
*ENANTIOSELECTIVE catalysis
*AMINATION
*DNA adducts
Subjects
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 76
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 61925853
- Full Text :
- https://doi.org/10.1021/jo102361h