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Metal–Organic Frameworks with Achiral/Monochiral Nano-Channels.

Authors :
Xiao-Yi Yi
Hua-Cai Fang
Zhi-Gang Gu
Zheng-Yuan Zhou
Yue-Peng Cai
Jian Tian
Praveen K. Thallapally
Source :
Crystal Growth & Design. Jul2011, Vol. 11 Issue 7, p2824-2828. 5p.
Publication Year :
2011

Abstract

Three pH/temperature-dependent 2D MOFs containing 1D nanotubular meso-helical chains were firstly synthesized from multidentate 2,4ˈ-H2bpdc. Crystal structure analysis shows that 2and 3are monochiral and the resultant crystals were not racemic as evidenced by the observation of strong signals in vibrational circular dichroism (VCD) and circular dichroism (CD) spectra. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
15287483
Volume :
11
Issue :
7
Database :
Academic Search Index
Journal :
Crystal Growth & Design
Publication Type :
Academic Journal
Accession number :
62325956
Full Text :
https://doi.org/10.1021/cg101618n