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Electrochemiluminescent Detection of Metal Cations Using a Ruthenium(II) Bipyridyl Complex...

Authors :
Muegge, Brian D.
Richter, Mark M.
Source :
Analytical Chemistry. 2/1/2002, Vol. 74 Issue 3, p547. 4p. 3 Diagrams, 2 Charts, 5 Graphs.
Publication Year :
2002

Abstract

Explores the effects of metal ions on the electroluminescence (ECL) properties of (bpy)[sub 2]Ru(AZA-bpy) (bpy=2,2'-bipyridine; AZA-bpy=4- (N-aza-18-crown-6-methyl-2,2'-bypiridine). Electrochemistry, photophysics and ECL of Ru(bpy)[sub 3][sup 2+]; Increases in ECL efficiency up to 20-fold that depend on both the concentration and nature of the metal ion.

Details

Language :
English
ISSN :
00032700
Volume :
74
Issue :
3
Database :
Academic Search Index
Journal :
Analytical Chemistry
Publication Type :
Academic Journal
Accession number :
6314604
Full Text :
https://doi.org/10.1021/ac010872z