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Precise Isomerization Polymerization of Alkenylcyclohexanes: Stereoregular Polymers Containing Six-Membered Rings along the Polymer Chain.
- Source :
-
Journal of the American Chemical Society . 7/27/2011, Vol. 133 Issue 29, p11106-11109. 4p. - Publication Year :
- 2011
-
Abstract
- Pd and Ni diimine complexes catalyze the isomerization polymerization of alkenylcyclohexanes to afford polymers composed of alternating trans-cyclohexane-1,4-diyl rings and oligomethylene spacers with high selectivity. The melting points of the polymers vary from 130 to 226 °C depending on length of the oligomethylene spacer. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ISOMERIZATION
*POLYMERS
*CYCLOHEXANE
*MELTING points
*PALLADIUM
*NICKEL
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 133
- Issue :
- 29
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 63892299
- Full Text :
- https://doi.org/10.1021/ja2043968