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Synthesis of bi- and tetracatenar highly fluorinated compounds for grafting on silicone materials
- Source :
-
Journal of Fluorine Chemistry . Oct2011, Vol. 132 Issue 10, p760-766. 7p. - Publication Year :
- 2011
-
Abstract
- Abstract: A series of highly fluorinated compounds bearing two or four perfluoroalkyl (R F ) chains, with a flexible or rigid core have been synthesized. Radical additions, nucleophilic addition or condensation reactions were implemented for these synthesis, using perfluoroalkylated iodides and alcohols and various type of substrates: bis(allylic) derivatives, epichlorhydrin, diacid derivatives. All compounds contain an unsaturated moiety (vinyl, allyl or internal double bond) to be grafted on silicone materials by a catalyzed hydrosilylation reaction. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 00221139
- Volume :
- 132
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Journal of Fluorine Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 64859849
- Full Text :
- https://doi.org/10.1016/j.jfluchem.2011.05.020