A new three-dimensional terbium-carboxylate framework possessing Tb2 and Tb4 clusters: Synthesis, structure, luminescent and magnetic properties

Abstract: A new three-dimensional terbium-carboxylate framework [Tb4L3(H2O)9]·7H2O (1) [(H4L=4,4′-(hexafluoroisopropylidene)diphthalic acid)] has been hydrothermally synthesized and structurally characterized. The framework contains Tb2 and Tb4 clusters, and exhibits an unprecedented 4-nodal (3,4,5,8)-connected topology. In addition, the thermogravimetric analysis, luminescent and magnetic properties were investigated. [Copyright &y& Elsevier]