Composite system based on biomolecules-functionalized multiwalled carbon nanotube and ionic liquid: Electrochemistry and electrocatalysis of tryptophane

Abstract: The combination of biomolecules-functionalized multiwalled carbon nanotube (MWNTs) and ionic liquid (IL) yields nanostructured biointerfaces, formed a novel kind of structurally uniform and bioelectrocatalytic activity material. Rutin was chosen as a model biomolecules to investigate the composite system. The MWNTs–Rutin–IL composite film was characterized by different methods including thermogravimetric analysis (TGA), UV–vis spectra, electrochemical impedance spectroscopy (EIS) and scanning electrochemical microscope (SECM). A pair of well-defined quasi reversible redox peaks of rutin was obtained at the MWNTs–Rutin–IL composite film modified glassy carbon electrode (GCE) by direct electron transfer between the rutin and the GCE electrode. Dramatically enhanced biocatalytic and electrocatalytic activity was exemplified at the MWNTs–Rutin–IL/GCE electrode by the oxidized of tryptophane. The oxidation peak currents of tryptophane in such modified electrode increased linearly with the concentrations of tryptophane in the range from 8×10−8 to 2×10−5 molL−1 with a detection limit of 3.0×10−8 molL−1. The unique composite material based on biomolecules-functionalized carbon nanotube and ionic liquid have wide potential applications in direct electrochemistry, biosensors, and biocatalysis. [Copyright &y& Elsevier]