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Atom-Efficient Assembly of 1,5-Oxygen-Bridged Medium-Sized Carbocycles by Sequential Combination of a Ru-Catalyzed Alkyne-Alkene Coupling and a Prins-Type Cyclization.
- Source :
-
Journal of the American Chemical Society . 4/24/2002, Vol. 124 Issue 16, p4218. 2p. 2 Diagrams, 1 Chart. - Publication Year :
- 2002
-
Abstract
- Examines the ruthenium-catalyzed alkyne-alkene coupling and a prins-type cyclization. Use of 1-trimethylsilyl-1-alkyn-3-ols and allyl ethers; Application of aromatic system as the nucleophilic partner; Assembly of a homologous oxygen-bridged system.
- Subjects :
- *RUTHENIUM
*ALKYNES
*RING formation (Chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 124
- Issue :
- 16
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 6834051
- Full Text :
- https://doi.org/10.1021/ja017804e