Efficient photodegradation of 4,4′-(propane-2,2-diyl)diphenol over biomolecule modified titanium dioxide under visible light irradiation

Abstract: A novel biomolecule (urushiol) grafted Degussa P25 hybrid nanoparticle (UP25) was synthesized, and its structure was characterized. The UP25 hybrid nanoparticle showed high photoactivity under visible light irradiation (λ≥420nm). 4,4′-(propane-2,2-diyl)diphenol (Bisphenol A, BPA) can easily approach to UP25 surface through the hydrophobic channels between alkyl groups in urushiol. BPA degradation rate constants were 1.02×10−3 min−1 and 4.96×10−3 min−1 over P25 and UP25, respectively. Radical quenching experiments proved that the superoxide radical anion (O2 −) mediated oxidation pathways were dominant for degradation of BPA. [Copyright &y& Elsevier]