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The Absolute Configuration of Chrysomelidial: A Widely Distributed Defensive Component Among Oribotririid Mites (Acari: Oribatida).
- Source :
-
Journal of Chemical Ecology . Jan2012, Vol. 38 Issue 1, p29-35. 7p. 3 Diagrams, 2 Charts, 1 Graph. - Publication Year :
- 2012
-
Abstract
- The absolute configuration of the iridoid monoterpene chrysomelidial from the oribatid mite, Austrotritia dentate Aoki, was elucidated by the GC-MS and GC comparisons with four synthetic stereoisomers of this well-known natural product. This identification was made possible by asymmetric synthesis of the known alcohol, (5 S,8 S)-chrysomelidiol. The GC retention time of diol derived from the natural oribatid dial agreed with that of the synthetic (5 S,8 S)-chrysomelidiol, confirming that the absolute configurations at C5 and C8 positions of the natural chrysomelidial are both S. Chrysomelidial was detected as a single or a major component in nine oribatid mites examined; thus, this compound is considered to be commonly distributed in Oribotririidae where it serves a defensive role. [ABSTRACT FROM AUTHOR]
- Subjects :
- *MONOTERPENES
*TERPENES
*IRIDOIDS
*MITES
*ALLOMONES
Subjects
Details
- Language :
- English
- ISSN :
- 00980331
- Volume :
- 38
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Journal of Chemical Ecology
- Publication Type :
- Academic Journal
- Accession number :
- 70842598
- Full Text :
- https://doi.org/10.1007/s10886-012-0064-3