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Development of ceramic sealant for solid oxide fuel cell application: Self-healing property, mechanical stability and thermal stability
- Source :
-
Journal of Power Sources . Apr2012, Vol. 204, p122-126. 5p. - Publication Year :
- 2012
-
Abstract
- Abstract: In this paper, a ceramic sealant (CaB2O4) is developed for the self-healing design of solid oxide fuel cells (SOFCs). The interface between this ceramic sealant and the anode-supported electrolyte, e.g., 8mole% yttria-stabilized zirconia (8YSZ), remains intact after sixty thermal cycles from 800°C to room temperature. An in situ observation verifies that the micro-indentation on the surface of this material can be healed when heating from room temperature to 920°C at a heating rate of 40°Cmin−1. In addition, the weight loss of CaB2O4, held at 850°C in air for 28 days, decreases from 3.26±0.73 for sealed species to 0.81±0.04mgcm−2 for fully crystallized species; meanwhile, the weight loss of CaB2O4, held at 850°C in wet forming gas (30vol% water vapor) for 28 days, decreases from 14.80±1.83 for sealed species to 6.36±0.64mgcm−2 for fully crystallized species. Combining with the good mechanical stability and thermal-stability, this self-healing ceramic sealant provides promising solution for the sealing challenge of planar SOFCs. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 03787753
- Volume :
- 204
- Database :
- Academic Search Index
- Journal :
- Journal of Power Sources
- Publication Type :
- Academic Journal
- Accession number :
- 71410640
- Full Text :
- https://doi.org/10.1016/j.jpowsour.2012.01.022